Zeaxanthin 7,8-dioxygenase

Zeaxanthin 7,8-dioxygenase
Identifiers
EC no.1.14.99.42
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BRENDABRENDA entry
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Zeaxanthin 7,8-dioxygenase (EC 1.14.99.42, zeaxanthin 7,8(7',8')-cleavage dioxygenase, CsZCD) is an enzyme with systematic name zeaxanthin:oxygen oxidoreductase (7,8-cleaving).[1] This enzyme catalyses the following chemical reaction

zeaxanthin + 2 O2 {\displaystyle \rightleftharpoons } crocetin dialdehyde + 2 (3S)-3-hydroxycyclocitral

Zeaxanthin 7,8-dioxygenase acts twice on zeaxanthin cleaving 3-hydroxycyclocitral off each 3-hydroxy end group.

References

  1. ^ Bouvier F, Suire C, Mutterer J, Camara B (January 2003). "Oxidative remodeling of chromoplast carotenoids: identification of the carotenoid dioxygenase CsCCD and CsZCD genes involved in Crocus secondary metabolite biogenesis". The Plant Cell. 15 (1): 47–62. doi:10.1105/tpc.006536. PMC 143450. PMID 12509521.

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1.14.11: 2-oxoglutarate1.14.13: NADH or NADPH1.14.14: reduced flavin or flavoprotein1.14.15: reduced iron–sulfur protein1.14.16: reduced pteridine (BH4 dependent)1.14.17: reduced ascorbate1.14.18-19: other1.14.99 - miscellaneous
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